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Volume 31
Main Index

Issue 01


1-Aza Sugars, Apparent Transition State Analogues of Equatorial Glycoside Formation/Cleavage
Mikael Bols
pp 1–8 DOI: 10.1021/ar970058r
Configurational Assignment of Polyene Macrolide Antibiotics Using the [13C]Acetonide Analysis
Scott D. Rychnovsky, Bruce N. Rogers, and Timothy I. Richardson
pp 9–17 DOI: 10.1021/ar960223n
Oxygen Production in Nature:  A Light-Driven Metalloradical Enzyme Process
Cecilia Tommos, Gerald T. Babcock
pp 18–25 DOI: 10.1021/ar9600188
Designing Dendrimers Based on Transition-Metal Complexes. Light-Harvesting Properties and Predetermined Redox Patterns
Vincenzo Balzani, Sebastiano Campagna, Gianfranco Denti, Alberto Juris, Scolastica Serroni, and Margherita Venturi
pp 26–34 DOI: 10.1021/ar950202d
Total Synthesis of Immunosuppressants:  Unified Strategies Exploiting Dithiane Couplings and σ-Bond Olefin Constructions
Amos B. Smith, III, Stephen M. Condon, and John A. McCauley
pp 35–46 DOI: 10.1021/ar960289i

Issue 02


Novel Electron-Transfer Reactions Mediated by Alkali Metals Complexed by Macrocyclic Ligand
Zbigniew Jedliński
pp 55–61 DOI: 10.1021/ar9702076
Addition of Free Radicals to C60
John R. Morton, Fabrizia Negri, and Keith F. Preston
pp 63–69 DOI: 10.1021/ar950120p
Transition-Metal Receptor Systems for the Selective Recognition and Sensing of Anionic Guest Species
Paul D. Beer
pp 71–80 DOI: 10.1021/ar9601555
Multifunctional and Chiral Porphyrins:  Model Receptors for Chiral Recognition
Hisanobu Ogoshi and Tadashi Mizutani
pp 81–89 DOI: 10.1021/ar9603165
Nucleation of First-Order Phase Transitions
David W. Oxtoby
pp 91–97 DOI: 10.1021/ar9702278

Issue 03


Homolytic Substitution:  A Molecular Ménage à Trois
John C. Walton
pp 99–107 DOI: 10.1021/ar970259v
Hydrogenation, Hydrogenolysis, and Desulfurization of Thiophenes by Soluble Metal Complexes:  Recent Achievements and Future Directions
Claudio Bianchini and Andrea Meli
pp 109–116 DOI: 10.1021/ar970029g
Ionic Channels in Biological Membranes:  Natural Nanotubes
Bob Eisenberg
pp 117–123 DOI: 10.1021/ar950051e
Design by Directed Evolution
Frances H. Arnold
pp 125–131 DOI: 10.1021/ar960017f
Carboranes:  A New Class of Weakly Coordinating Anions for Strong Electrophiles, Oxidants, and Superacids
Christopher A. Reed
pp 133–139 DOI: 10.1021/ar970230r
Naturally Occurring Organohalogen Compounds
Gordon W. Gribble
pp 141–152 DOI: 10.1021/ar9701777

Issue 04


In Favor of Scientific Debate
pp 153–153 DOI: 10.1021/ar9804830
Intermediates in the Reactions of Fenton Type Reagents
Cheves Walling
pp 155–157 DOI: 10.1021/ar9700567
A Radical Account of “Oxygenated Fenton Chemistry” 1
Philip A. MacFaul, D. D. M. Wayner, and K. U. Ingold
pp 159–162 DOI: 10.1021/ar970057z
Structural Basis of Protein Kinase C Activation by Tumor Promoters
Yoshito Kishi and Robert R. Rando
pp 163–172 DOI: 10.1021/ar9600751
Foldamers:  A Manifesto
Samuel H. Gellman
pp 173–180 DOI: 10.1021/ar960298r
Ionic Mobility and Ultrafast Solvation:  Control of a Slow Phenomenon by Fast Dynamics
Biman Bagchi and Ranjit Biswas
pp 181–187 DOI: 10.1021/ar970226f
First-Principles Quantum Chemical Studies of Porphyrins
Abhik Ghosh
pp 189–198 DOI: 10.1021/ar950033x

Issue 05


Chemical Sensors Special Issue
Christopher S. Foote
pp 199–199 DOI: 10.1021/ar980480n
Chemical Sensors
Antonio J. Ricco, Richard M. Crooks
pp 200–200 DOI: 10.1021/ar980479o
The Molecular Wire Approach to Sensory Signal Amplification
Timothy M. Swager
pp 201–207 DOI: 10.1021/ar9600502
Molecular Recognition in Lamellar Solids and Thin Films
Thomas E. Mallouk and Julia A. Gavin
pp 209–217 DOI: 10.1021/ar970038p
New Organic Materials Suitable for Use in Chemical Sensor Arrays
Richard M. Crooks, Antonio J. Ricco
pp 219–227 DOI: 10.1021/ar970246h
Color and Chromism of Polydiacetylene Vesicles
Sheldon Okada, Susan Peng, Wayne Spevak, and Deborah Charych
pp 229–239 DOI: 10.1021/ar970063v
Chemical Modulation of Work Function as a Transduction Mechanism for Chemical Sensors
JiřÍ Janata and Mira Josowicz
pp 241–248 DOI: 10.1021/ar9700668
Hydrogen Sensing Mechanisms of Metal−Insulator Interfaces
Lars-Gunnar Ekedahl, Mats Eriksson, and Ingemar Lundström
pp 249–256 DOI: 10.1021/ar970068s
Studies of Potential Generation Across Membrane Sensors at Interfaces and through Bulk
Richard P. Buck and Erno Lindner
pp 257–266 DOI: 10.1021/ar9700623
Fiber Optic Imaging Sensors
David R. Walt
pp 267–278 DOI: 10.1021/ar970069k
Kinetically Controlled Chemical Sensing Using Micromachined Structures
Steve Semancik and Richard Cavicchi
pp 279–287 DOI: 10.1021/ar970071b
Surface Acoustic Wave Chemical Sensor Arrays:  New Chemically Sensitive Interfaces Combined with Novel Cluster Analysis To Detect Volatile Organic Compounds and Mixtures
Antonio J. Ricco, Richard M. Crooks, and Gordon C. Osbourn
pp 289–296 DOI: 10.1021/ar9600749
Visual-Empirical Region-of-Influence Pattern Recognition Applied to Chemical Microsensor Array Selection and Chemical Analysis
G. C. Osbourn, J. W. Bartholomew, A. J. Ricco, and G. C. Frye
pp 297–305 DOI: 10.1021/ar970070j
Modular Sensor Systems for Gas Sensing and Odor Monitoring:  The MOSES Concept
Jan Mitrovics, Heiko Ulmer, Udo Weimar, and Wolfgang Göpel
pp 307–315 DOI: 10.1021/ar970064n
Microfabricated Biosensors and Microanalytical Systems for Blood Analysis
Imants R. Lauks
pp 317–324 DOI: 10.1021/ar9700670

Issue 06


The Silylium Ion Problem, R3Si+. Bridging Organic and Inorganic Chemistry
Christopher A. Reed
pp 325–332 DOI: 10.1021/ar960132q
Biotransformations in the Synthesis of Enantiopure Bioactive Molecules
Carl R. Johnson
pp 333–341 DOI: 10.1021/ar970013q
Protein Charge Ladders, Capillary Electrophoresis, and the Role of Electrostatics in Biomolecular Recognition
Jeffrey D. Carbeck, Ian J. Colton, Jinming Gao, and George M. Whitesides
pp 343–350 DOI: 10.1021/ar970255q
NMR and Spin Relaxation in Dimers
Valeria Clementi and Claudio Luchinat
pp 351–361 DOI: 10.1021/ar960159+
Enzyme Bioelectrochemistry in Cast Biomembrane-Like Films
James F. Rusling
pp 363–369 DOI: 10.1021/ar970254y
Molecular Recognition at Air−Water and Related Interfaces:  Complementary Hydrogen Bonding and Multisite Interaction
Katsuhiko Ariga and Toyoki Kunitake
pp 371–378 DOI: 10.1021/ar970014i

Issue 07


Kinetic Method of Making Thermochemical Determinations:  Advances and Applications
R. Graham Cooks and Philip S. H. Wong
pp 379–386 DOI: 10.1021/ar960242x
Gas-Phase Ozonolysis of Alkenes. Recent Advances in Mechanistic Investigations
Osamu Horie and Geert K. Moortgat
pp 387–396 DOI: 10.1021/ar9702740
Enzyme Catalysis:  Beyond Classical Paradigms
Amnon Kohen and Judith P. Klinman
pp 397–404 DOI: 10.1021/ar9701225
Molecular Machines
Vincenzo Balzani, Marcos Gómez-López, and J. Fraser Stoddart
pp 405–414 DOI: 10.1021/ar970340y
Chemistry at the Surfaces of Ice and Sulfuric Acid:  Toward an Understanding of Adsorption at Molecular Solids
Jeffrey T. Roberts
pp 415–421 DOI: 10.1021/ar950205q
Diaminoarylnickel(II) “Pincer” Complexes:  Mechanistic Considerations in the Kharasch Addition Reaction, Controlled Polymerization, and Dendrimeric Transition Metal Catalysts
Robert A. Gossage, Lucia A. van de Kuil, and Gerard van Koten
pp 423–431 DOI: 10.1021/ar970221i

Issue 08


Theory of Two-State Cooperative Folding of Proteins
Ming-Hong Hao and Harold A. Scheraga
pp 433–440 DOI: 10.1021/ar960288q
Hydrogen Atom Abstraction by Metal−Oxo Complexes:  Understanding the Analogy with Organic Radical Reactions
James M. Mayer
pp 441–450 DOI: 10.1021/ar970171h
Oxygen Capture by Sulfur in Nickel Thiolates
Craig A. Grapperhaus and Marcetta Y. Darensbourg
pp 451–459 DOI: 10.1021/ar950048v
High-Frequency EPR Spectroscopy of Large Metal Ion Clusters: From Zero Field Splitting to Quantum Tunneling of the Magnetization
Anne-Laure Barra, Louis-Claude Brunel, Dante Gatteschi, Luca Pardi, and Roberta Sessoli
pp 460–466 DOI: 10.1021/ar960157p
Zero Kinetic Energy Spectroscopy
Andrew Held and Edward W. Schlag
pp 467–473 DOI: 10.1021/ar9702987
Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids
Omar M. Yaghi, Hailian Li, Charles Davis, David Richardson, and Thomas L. Groy
pp 474–484 DOI: 10.1021/ar970151f
Heterogeneous Catalysts for Liquid-Phase Oxidations:  Philosophers' Stones or Trojan Horses?
Roger A. Sheldon, Martin Wallau, Isabel W. C. E. Arends, and Ulf Schuchardt
pp 485–493 DOI: 10.1021/ar9700163
Novel Amine Chemistry Based on DMAP-Catalyzed Acylation
Ulf Ragnarsson and Leif Grehn
pp 494–501 DOI: 10.1021/ar980001k
Recognition of DNA, RNA, and Proteins by Circular Oligonucleotides
Eric T. Kool
pp 502–510 DOI: 10.1021/ar9602462
Conical Intersections:  Diabolical and Often Misunderstood
David R. Yarkony
pp 511–518 DOI: 10.1021/ar970113w

Issue 09


Fulleropyrrolidines:  A Family of Full-Fledged Fullerene Derivatives
Maurizio Prato, Michele Maggini
pp 519–526 DOI: 10.1021/ar970210p
Photochemistry of Halide Ion−Molecule Clusters:  Dipole-Bound Excited States and the Case for Asymmetric Solvation
Caroline E. H. Dessent, Jun Kim, and Mark A. Johnson
pp 527–534 DOI: 10.1021/ar950061f
Hexacoordinate Phosphorus via Donor Interaction. Implications Regarding Enzymatic Reaction Intermediates
Robert R. Holmes
pp 535–542 DOI: 10.1021/ar9702583
Heme Oxygenase Mechanism:  Evidence for an Electrophilic, Ferric Peroxide Species
Paul R. Ortiz de Montellano
pp 543–549 DOI: 10.1021/ar960207q
Catalytic Functionalization of Carbon−Hydrogen and Carbon−Carbon Bonds in Protic Media
Ayusman Sen
pp 550–557 DOI: 10.1021/ar970290x
Cones and Tubes:  Geometry in the Chemistry of Carbon
Thomas W. Ebbesen
pp 558–566 DOI: 10.1021/ar960168i
Inducing and Viewing Bond Selected Chemistry with Tunneling Electrons
Wilson Ho
pp 567–573 DOI: 10.1021/ar9501784
Atmospheric Chemistry of Biogenic Organic Compounds
Roger Atkinson and Janet Arey
pp 574–583 DOI: 10.1021/ar970143z
New Synthetic Methodologies for Carbon−Carbon Double Bond Formation
Yanchang Shen
pp 584–592 DOI: 10.1021/ar970060i
Electrochemistry of Fullerenes and Their Derivatives
Luis Echegoyen and Lourdes E. Echegoyen
pp 593–601 DOI: 10.1021/ar970138v

Issue 10


Diverse Methods for Medium Ring Synthesis
Gary A. Molander
pp 603–609 DOI: 10.1021/ar960101v
Transition Metal-Containing Rotaxanes and Catenanes in Motion: Toward Molecular Machines and Motors
Jean-Pierre Sauvage
pp 611–619 DOI: 10.1021/ar960263r
Monitoring the Progress and the Yield of Solid-Phase Organic Reactions Directly on Resin Supports
Bing Yan
pp 621–630 DOI: 10.1021/ar970327d
Photochemical Exploration of Reaction Dynamics at Catalytic Metal Surfaces:  From Ballistics to Statistics
Ian Harrison
pp 631–639 DOI: 10.1021/ar9700926
Fluorous Biphase Chemistry
István T. Horváth
pp 641–650 DOI: 10.1021/ar970342i
Observation of Radical Cations by Swiftness or by Stealth
David W. Werst and Alexander D. Trifunac
pp 651–657 DOI: 10.1021/ar970234w
Some Recent Advances and Remaining Questions Regarding Unimolecular Rate Theory
William L. Hase
pp 659–665 DOI: 10.1021/ar970156c
Asymmetric Catalysis. A Comparative Study of the Mechanisms of Intramolecular Hydroacylation and Hydrosilation
Brice Bosnich
pp 667–674 DOI: 10.1021/ar970095i
Hyper-Rayleigh Scattering in Isotropic Solution
Eric Hendrickx, Koen Clays, and André Persoons
pp 675–683 DOI: 10.1021/ar960233o
Solid-Phase Synthesis of Oligosaccharides and Glycoconjugates by the Glycal Assembly Method:  A Five Year Retrospective
Peter H. Seeberger and Samuel J. Danishefsky
pp 685–695 DOI: 10.1021/ar9600648

Issue 11


Protein Folding Special Issue
Joan Selverstone Valentine
pp 697–697 DOI: 10.1021/ar980087h
Protein Folding
Jay R. Winkler and Harry B. Gray
pp 698–698 DOI: 10.1021/ar980086p
Laser Temperature Jump Induced Protein Refolding
Martin Gruebele, Jobiah Sabelko, Richard Ballew, and John Ervin
pp 699–707 DOI: 10.1021/ar970083x
Infrared Studies of Fast Events in Protein Folding
R. Brian Dyer, Feng Gai, and William H. Woodruff, Rudolf Gilmanshin and Robert H. Callender
pp 709–716 DOI: 10.1021/ar970343a
Kinetic and Structural Analysis of Submillisecond Folding Events in Cytochrome c
M. C. Ramachandra Shastry, J. Michael Sauder, and Heinrich Roder
pp 717–725 DOI: 10.1021/ar970086+
Cytochrome c Folding and Unfolding:  A Biphasic Mechanism
Syun-Ru Yeh, Sanghwa Han, and Denis L. Rousseau
pp 727–736 DOI: 10.1021/ar970084p
Fast and Slow Folding in Cytochrome c
S. Walter Englander, Tobin R. Sosnick, Leland C. Mayne, Mark Shtilerman, Phoebe X. Qi, and Yawen Bai
pp 737–744 DOI: 10.1021/ar970085h
Kinetics and Dynamics of Loops, α-Helices, β-Hairpins, and Fast-Folding Proteins
William A. Eaton, Victor Muñoz, Peggy A. Thompson, Eric R. Henry, and James Hofrichter
pp 745–753 DOI: 10.1021/ar9700825
Protein Folding Triggered by Electron Transfer
Jason R. Telford, Pernilla Wittung-Stafshede, Harry B. Gray, and Jay R. Winkler
pp 755–763 DOI: 10.1021/ar970078t
Alternative Explanations for “Multistate” Kinetics in Protein Folding:  Transient Aggregation and Changing Transition-State Ensembles
Mikael Oliveberg
pp 765–772 DOI: 10.1021/ar970089m
Real-Time NMR Studies of Protein Folding
Nico A. J. van Nuland, Vincent Forge, Jochen Balbach, and Christopher M. Dobson
pp 773–780 DOI: 10.1021/ar970079l

Issue 12


Self-Assembled Polyelectrolyte−Surfactant Complexes in Nonaqueous Solvents and in the Solid State
Willam J. MacKnight, Ekaterina A. Ponomarenko, and David A. Tirrell
pp 781–788 DOI: 10.1021/ar960309g
Giant Vesicles:  Imitating the Cytological Processes of Cell Membranes
Fredric M. Menger, Miglena I. Angelova
pp 789–797 DOI: 10.1021/ar970103v
Mechanisms of Initial Dissociative Chemisorption of Oxygen on Transition-Metal Surfaces
Peter D. Nolan, M. Clay Wheeler, John E. Davis, and C. Buddie Mullins
pp 798–804 DOI: 10.1021/ar960278p
Rational Development of Practical Catalysts for Aromatic Carbon−Nitrogen Bond Formation
John P. Wolfe, Seble Wagaw, Jean-François Marcoux, and Stephen L. Buchwald
pp 805–818 DOI: 10.1021/ar9600650
F1-ATPase:  A Molecular Motor That Hydrolyzes ATP with Sequential Opening and Closing of Catalytic Sites Coupled to Rotation of Its γ Subunit
William S. Allison
pp 819–826 DOI: 10.1021/ar960257v
Gaseous Arenium Ions at Atmospheric Pressure:  Elementary Reactions and Internal Solvation Effects
Simonetta Fornarini and Maria Elisa Crestoni
pp 827–834 DOI: 10.1021/ar960247u
Cationic Polymerization Astronomy. Synthesis of Polymer Stars by Cationic Means
J. P. Kennedy and S. Jacob
pp 835–841 DOI: 10.1021/ar950065k
The Role of Bridging Ligands in Controlling Electronic and Magnetic Properties in Polynuclear Complexes
Jon A. McCleverty and Michael D. Ward
pp 842–851 DOI: 10.1021/ar970315s
Carbon−Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides
John F. Hartwig
pp 852–860 DOI: 10.1021/ar970282g
Polymerization of Preformed Self-Organized Assemblies
David F. O'Brien, Bruce Armitage, Alto Benedicto, Doyle E. Bennett, Henry G. Lamparski, Youn-Sik Lee, Warunee Srisiri, and Thomas M. Sisson
pp 861–868 DOI: 10.1021/ar970140m